Cycloaddition of Dipolar Trimethylenemethane to C70 Promoted by a Trace Amount of Water
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- Shigeru Yamago
- Department of Synthetic Chemistry & Biological Chemistry, Kyoto University
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- Eiichi Nakamura
- Department of Chemistry, The University of Tokyo
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Abstract
<jats:title>Abstract</jats:title> <jats:p>Thermal cycloaddition of a dipolar TMM to C70 at 80–90 °C in a “wet” solvent affords a mixture of the acetal 2 and the C70-carboxylic acid ester 3. The former (as well as its C60 analog) undergoes isomerization to the latter at 120-160 °C.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 25 (5), 395-396, 1996-05-01
Oxford University Press (OUP)
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Details
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- CRID
- 1360283694085903104
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- NII Article ID
- 10003740269
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- NII Book ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles