Cycloaddition of Dipolar Trimethylenemethane to C70 Promoted by a Trace Amount of Water

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Thermal cycloaddition of a dipolar TMM to C70 at 80–90 °C in a “wet” solvent affords a mixture of the acetal 2 and the C70-carboxylic acid ester 3. The former (as well as its C60 analog) undergoes isomerization to the latter at 120-160 °C.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 25 (5), 395-396, 1996-05-01

    Oxford University Press (OUP)

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