Effect of Ceramics Addition on Formation Tendency of Amorphous Phase in La<SUB>55</SUB>Al<SUB>25</SUB>Ni<SUB>20</SUB> Alloy

  • Haibara Teruo
    Advanced Technology Research Laboratories, Nippon Steel Corporation
  • Ozaki Kimihiro
    Material Processing Department, National Industrial Research Institute of Nagoya
  • Kobayashi Keizo
    Material Processing Department, National Industrial Research Institute of Nagoya
  • Nishio Toshiyuki
    Material Processing Department, National Industrial Research Institute of Nagoya
  • Miwa Kenji
    Material Processing Department, National Industrial Research Institute of Nagoya

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  • Effect of Ceramics Addition on Formation Tendency of Amorphous Phase in La55Al25Ni20 Alloy
  • Effect of Ceramics Addition on Formatio

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Abstract

The effect of additional ceramic powder on the formation tendency of an amorphous phase in a La55Al25Ni20 alloy was investigated by water quenching of a molten alloy. The specimens were 12 mm in diameter and 6 mm thick. In the alloy without ceramic powder, the amorphous phase forms only near the surface of the specimen. By the addition of 6 vol% TiB2 powder, it was possible to produce a homogeneous alloy specimen with amorphous and crystalline phases. In order to analyze the role played by ceramic powder in this process, various kinds of ceramic powders were added. TiC powder played the same role as TiB2 powder in this process, but TiN and ZrB2 powders did not. A crystalline phase about 20 μ in thickness was observed at the surface of TiB2 in the optical microstructure. By EPMA, this crystalline phase was confirmed to have a composition of poorer La and richer Al, Ni than the matrix phase. Since the crystal preferentially nuclcate at TiB2 surface and grows slowly, the matrix phase would easily form an amorphous state.

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