Synthesis and Characterization of a Peroxovanadium(V) Complex Containing N-Carboxymethylhistidine as a Model for the Vanadium Haloperoxidase Enzymes

• Kan Kanamori

  Department of Chemistry, Faculty of Science, Toyama University

• Kazuya Nishida

  Department of Chemistry, Faculty of Science, Toyama University

• Nanako Miyata

  Department of Chemistry, Faculty of Science, Toyama University

• Ken-ichi Okamoto

  Department of Chemistry, University of Tsukuba

抄録

The peroxovanadium(V) complex containing N-carboxymethylhistidine (cmhist) was synthesized and structurally characterized by X-ray analysis as a model compound for the vanadium-dependent haloperoxidase enzymes. The complex takes a heptacoordinate structure consisting of a quadridentate cmhist ligand, a side-on bound peroxo group, and an oxo group. The coordination polyhedron is a distorted pentagonal bipyramid.

収録刊行物

• Chemistry Letters

  Chemistry Letters 27 (12), 1267-1268, 1998-12-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694086172928
• NII論文ID: 10004281935
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.1998.1267
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/27/12/1267/56072075/cl.1998.1267.pdf
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