A Molecular Structure of Bis(N-octylethylenediamine)zinc(II) Nitrate in Crystal and the Aggregations in Wet Chloroform and Benzene Solutions

• Masayasu Iida

  Department of Chemistry, Faculty of Science, Nara Women’s University

• Tomoaki Tanase

  Department of Chemistry, Faculty of Science, Nara Women’s University

• Norie Asaoka

  Department of Chemistry, Faculty of Science, Nara Women’s University

• Akiko Nakanishi

  Department of Chemistry, Faculty of Science, Nara Women’s University

抄録

Zinc complex with N-octylethylenediamine( = OE), Zn(OE)2(NO3)2, was prepared and its molecular structure was determined on the basis of an X-ray crystallographic analysis. It was revealed that in the octahedral molecular structure the nitrato groups are trans and the octyl chains are transoid. Extensive aggregations of this complex in wet chloroform and wet benzene systems were also studied using 1H NMR self-diffusions for the solvents and the zinc complex.

収録刊行物

• Chemistry Letters

  Chemistry Letters 27 (12), 1275-1276, 1998-12-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360565169062885248
• NII論文ID: 10004282002
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.1998.1275
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/27/12/1275/56072143/cl.1998.1275.pdf
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