Synthesis and Structure of NLO-active 8,8-Dicyano-3-(4′-<i>N</i>,<i>N</i>-dimethylamino)phenylheptafulvene

  • Hiroyuki Otani
    Department of Environmental Science, Faculty of Education and Human Sciences, Yokohama National UniversityYokohama
  • Jin Mizuguchi
    Department of Applied Physics, Faculty of Engineering, Yokohama National UniversityYokohama

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<jats:title>Abstract</jats:title> <jats:p>Some new 8,8-dicyanophenylheptafulvene derivatives have been synthesized, among which the title compound 1a is found to crystallize in the polar space group of P1 showing non-linear optical characteristics. Compound 1a is composed of a strong acceptor of the dicyanomethylene group and a strong donor of the dimethylamino group, both of which are combined with the π-conjugated phenylheptafulvene skeleton.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 28 (5), 389-390, 1999-05-01

    Oxford University Press (OUP)

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