Photoredox Ability of a Hexarhenium(III) Cluster [Re6(μ3-S)8Cl6]4−

  • Natsuki Kobayashi
    Division of Chemistry, Graduate School of Science, Hokkaido University
  • Shoji Ishizaka
    Division of Chemistry, Graduate School of Science, Hokkaido University
  • Takashi Yoshimura
    Division of Chemistry, Graduate School of Science, Hokkaido University
  • Haeng-Boo Kim
    Division of Chemistry, Graduate School of Science, Hokkaido University
  • Yoichi Sasaki
    Division of Chemistry, Graduate School of Science, Hokkaido University
  • Noboru Kitamura
    Division of Chemistry, Graduate School of Science, Hokkaido University

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<jats:title>Abstract</jats:title> <jats:p>The photoredox ability of a hexarhenium(III) cluster, (n-Bu4N)44+[Re6(μ3-S)8Cl6]4−, was examined in acetonitrile on the basis of emission quenching experiments of the cluster by several neutral electron acceptors. The quenching rate constants and the relevant activation parameters indicated that the hexarhenium(III) cluster acted as a useful photoredox sensitizer towards various electron acceptors.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 29 (3), 234-235, 2000-03-01

    Oxford University Press (OUP)

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