Easy Preparation and Prominent Gelation of New Gelator Based on <scp>l</scp>-Lysine

• Hanabusa Kenji

  Graduate School of Science and Technology, Shinshu University

• Nakayama Hiroko

  Faculty of Textile Science and Technology, Shinshu University

• Kimura Mutsumi

  Faculty of Textile Science and Technology, Shinshu University

• Shirai Hirofusa

  Faculty of Textile Science and Technology, Shinshu University

書誌事項

タイトル別名

• Easy Preparation and Prominent Gelation of New Gelator Based on <FONT SIZE="-2">L</FONT>-Lysine

抄録

A new prominent gelator 1, N^ε-lauroyl-N^α-stearylaminocarbonyl-L-lysine ethyl ester was effortlessly prepared by esterification of N^ε-lauroyl-L-lysine and addition of n-octadecyl isocyanate in a total yield of 89%. Gelator 1 was capable of gelling up a wide variety of organic fluids. A comparison of the gelation ability of structurally related compounds clarified that not only the introduction of long-chain alkyl but also more importantly the ureylene segment connecting the α-amino group and the alkyl chain are required for effective gelation.

収録刊行物

• Chemistry Letters

  Chemistry Letters 29 (9), 1070-1071, 2000

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390282679551528320
• NII論文ID: 10004695888
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2000.1070
• COI: 1:CAS:528:DC%2BD3cXmsFWjur4%3D
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/29/9/1070/56077505/cl.2000.1070.pdf
• 本文言語コード: en
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