A Novel Photocatalysis of Phosphorous Porphyrins for Hydration of Benzonitrile

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  • Takeshi Igarashi
    Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
  • Katsuaki Konishi
    Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
  • Takuzo Aida
    Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo

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<jats:title>Abstract</jats:title> <jats:p>Under irradiation with visible light, oxophosphorous porphyrins [(EtioP)PR(=O), 1 (R = Ph) and 2 (R = Et); EtioP = etioporphyrinato I] and phenyl(methoxy)phosphorous porphyrin chloride [[(EtioP)PPh(OMe)]Cl, 3] catalyzed hydration of benzonitrile to benzamide in alkaline methanol.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 27 (10), 1039-1040, 1998-10-01

    Oxford University Press (OUP)

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