Anion Selectivities of Dibutyltin Dihalides as Neutral Carriers for Ion-Selective Electrodes.

• MORIUCHI-KAWAKAMI Takayo

  Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology

• AOTO Hiroshi

  Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology

• TAKEDA Naotake

  Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology

• FUJIMORI Keiichi

  Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology

• SHIBUTANI Yasuhiko

  Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology

Abstract

Di-n-butyltin dihalides (Bu₂SnY₂, Y=Cl, I, OMe) behaved as neutral carriers for anion-selective electrodes. A variety of selectivity patterns have been obtained by using Bu₂SnY₂ which differ in the electronegative substituents Y on the Sn atom. However, all electrodes containing Bu₂SnY₂ provided the highest degree of selectivity for the SCN^- ion. The interaction of Bu₂SnY₂ with the SCN^- ion was studied in the organic solution by means of ¹³C NMR spectroscopy. In the case of the addition of NaSCN, a significant increase of the value of ¹J(¹¹⁹Sn^-13Cα) was observed in the 2.0 M CDCl₃ solution of Bu₂SnCl₂.

Journal

• Analytical Sciences

  Analytical Sciences 16 (3), 303-306, 2000

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390001204255269120
• NII Article ID: 130004440222
• NII Article ID: 10004705699
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.16.303
• COI: 1:CAS:528:DC%2BD3cXitFegurs%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 5312289
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5312289
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.16.303.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.16.303/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/16/3/16_3_303/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed