Peroxidase-Like Activity of Ion Exchange Resins Modified with Metal-Porphine in Fluorescent Flow Injection Analysis.

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Peroxidase-like activity of anion-exchange resins modified with metal-tetrakis(sulfophenyl)porphine (M-TSPPr, M=Fe3+, Co3+ and Mn3+) were evaluated in the flow injection analysis of hydrogen peroxide using a fluorescent dimmer-formation reaction from chromogens, such as tyramine. A column (2.1 mm×50 mm) packed with Fe3+-TSPPr and a tube (0.8 mm×50 mm) packed with Mn3+-TSPPr accelerated the dimmer-formation reaction, indicating that they exhibit peroxidase-like activity just like the peroxidase-immobilized-column in the flow injection system.

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  • Analytical Sciences

    Analytical Sciences 15 (9), 841-846, 1999

    社団法人 日本分析化学会

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