Application of Thiacrown Ethers as Ligands for Lead-Selective Electrodes.

• RADECKA Hanna

  Polish Academy of Sciences, Institute of Animal Reproduction and Food Research, Division of Food Science

• RADECKI Jerzy

  Polish Academy of Sciences, Institute of Animal Reproduction and Food Research, Division of Food Science

• DEHAEN Wim

  Department of Chemistry

Abstract

Lead-selective solvent polymeric membrane electrodes based on selected thiacrown ethers, poly(vinyl chloride) (PVC), the plasticizer bis(2-ethylhexyl)phthalate [“dioctyl phthalate” (DOP)], and potassium tetrakis(p-chlorophenyl)borate (KTpCPB) (50mol%, relative to the ionophore) as anionic sites are described. The potential measurements were done in the presence of acetate buffer (pH 4.00) and for successively diluted stock solutions of 10^-2 M Pb(NO₃)₂. Potential-pH profiles of membranes based on selected thiacrown ethers demonstrated lack of H⁺ interference within a wide pH range. The effect of the sample solution composition as well as the inner reference solution on the selectivity and detection range were demonstrated.

Journal

• Analytical Sciences

  Analytical Sciences 15 (11), 1109-1114, 1999

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390001204252586368
• NII Article ID: 10004708317
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.15.1109
• COI: 1:CAS:528:DyaK1MXnsVGhtLg%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 4907941
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4907941
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.15.1109.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.15.1109/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/15/11/15_11_1109/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed