Preparation and Characterization of Alkylphosphonate-Modified Magnesia-Zirconia Composite for Reversed-Phase Liquid Chromatography.

• FENG Yu-Qi

  Department of Chemistry, Wuhan University

• ZHANG Qing-He

  Department of Chemistry, Wuhan University

• DA Shi-Lu

  Department of Chemistry, Wuhan University

• ZHANG Yan

  Laboratory of MRAMP of China

Abstract

A new material: magnesia-zirconia composite modified by an alkylphosphonate can be used as a reversed-phase stationary phase for high-performance liquid chromatography. The new material was characterized by elemental analysis, FTIR and ¹³C solid state NMR spectrometry. The pH stability of the new material was investigated using biphenyl and N,N′-dimethylaniline as probes with methanol-water (60:40, v/v) as a mobile phase, after the column was continuously purged with solutions at extreme pH 2 and pH 11. The chromatographic performance of the new material was studied by using polycyclic aromatic hydrocarbons (PAHs) and basic compounds as probes. The results indicate that the new material is of high pH stability and can be used for separation of PAHs and basic compounds.

Journal

• Analytical Sciences

  Analytical Sciences 16 (6), 579-583, 2000

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390282679233650944
• NII Article ID: 10004954972
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.16.579
• COI: 1:CAS:528:DC%2BD3cXksVOitrs%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 5380246
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5380246
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.16.579.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.16.579/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/16/6/16_6_579/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed