傾斜機能材料  高重力場とゾル‐ゲル法を用いたSiO2‐TiO2系傾斜ガラスの作製

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タイトル別名
  • Preparation of SiO2-TiO2 Graded Glass by Using High Gravity Field Combined with Sol-Gel Method.
  • コウ ジュウリョクバ ト ゾル ゲルホウ オ モチイタ SiO2 Ti02ケイ ケイシャ ガラス ノ サクセイ

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A method to prepare the multi-component oxide glass with graded structure was proposed. This method is based on the facts that colloid particles can sediment during a sol-gel transition process under comparatively low gravity field, and the resultant gel can be converted into glass at lower temperature treatment than a conventional method. The graded structure was formed by centrifuging (10, 000g level) the Si and Ti mixed colloids, and immobilized by removal of solvent at 90°C. This graded precursor gel was heated to 900°C to convert into a glass state. The proper condition to prepare the graded glass was examined especially focusing on the growth time of colloids before the centrifugation. A transparent SiO2-TiO2 glass with molecular-scale graded structure was obtained in many trials.

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