Chloride Ion Conducting Characteristics in Rare Earth Oxychlorides

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  • Nobuhito Imanaka
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Koji Okamoto
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Gin-ya Adachi
    Department of Applied Chemistry, Faculty of Engineering, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>Chloride ion (Cl−) conducting characteristics were investigated in calcium doped lanthanum oxychlorides which show a high stability even in a high humid atmosphere and at an elevated temperature. The Cl− ion conductivity of the oxychloride is approximately 10−4.5 S·cm−1 at 700 °C and the Cl− ion transference number is almost unity. The development of new types of Cl− ion conducting solid electrolytes with a high durability opens a door to realize a new application for functional materials.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 30 (2), 130-131, 2001-02-01

    Oxford University Press (OUP)

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