Electrochemical Oxidation of α,β-Unsaturated Ketones

• Tohru Takahashi

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Tetsuji Nakagawa

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Naomi Sakai

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Masakazu Sono

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Yoshikazu Shizuri

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

抄録

α,β-Unsaturated ketones were successfully oxidized by using electrochemical method. In this oxidation reaction, allylic methyl or methylene groups were converted into acetoxylmethyl group or methoxy carbonyl group. In contrast, these unsaturated ketones were stable to Sharpless’s method (a combination of selenium dioxide and t butyl hydroperoxide).

収録刊行物

• Chemistry Letters

  Chemistry Letters 22 (1), 177-180, 1993-01-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360565169062178304
• NII論文ID: 10006880950
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.1993.177
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/22/1/177/56065593/cl.1993.177.pdf
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