油性汚れの酸化変質とその洗浄に関する研究 (第4報)

書誌事項

タイトル別名
  • Oxidation and Detergency of Oily Soil. IV
  • ユセイ ヨゴレ ノ サンカ ヘンシツ ト ソノ センジョウ ニ カンスル ケン
  • Removal of Oxidation Products of Linoleic Acid
  • リノール酸酸化生成物の除去

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抄録

The oxidation products of linoleic acid were isolated and their removal from fabrics was investigated. Hydroxyoctadecadienoate was isolated by HPLC using acetonitrile/water (8/2 by volume) as a mobile phase at a retention time of 4.6 min. Two dimeric compounds were separated similarly using acetonitrile/tetrahydrofuran/water (6/3/1 by volume) at 6.0 and 9.6 min. All three compounds were quantitated by HPLC, as indicated by the good linear relationship between peak area and content of each.<BR>Removal efficiency from fabrics by SDS decreased in the order of hydroxyoctadecadienoate, linoleate, and two the dimeric compounds. The same order was observed when linoleate and its oxidation products were mixed.

収録刊行物

  • 油化学

    油化学 43 (2), 137-140, 1994

    公益社団法人 日本油化学会

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