Experimental Study on Enrichment of Low evel NO by Means of Adsorption.

  • WATANABE FUJIO
    Department of Energy Engineering & Science, Graduate School of Engineering Nagoya University
  • UEKI TOMOYA
    Department of Energy Engineering & Science, Graduate School of Engineering Nagoya University Mitsui Chemical Co. Ltd
  • KATO DAISAKU
    Department of Energy Engineering & Science, Graduate School of Engineering Nagoya University
  • MATSUDA HITOKI
    Research Cemter for Advanced Waste and Emision Management Nagoya University
  • HASATANI MASANOBU
    Department of Energy Engineering & Science, Graduate School of Engineering Nagoya University
  • SHIOMI NIRO
    Research & Development Center Kanebo, LTD.
  • MARUMO CHISATO
    Research & Development Center Kanebo, LTD.

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Other Title
  • 吸着による低濃度NOの濃縮に関する実験的検討
  • キュウチャク ニ ヨル テイノウド NO ノ ノウシュク ニ カンスル ジッケンテキ ケントウ

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Abstract

For reducing environmental discharge of NOx below 1 ppm, the authors propose a minimum NOx emission system comprised of an absorption process that can concentrate low level NOx coupled with a de-NOx;low level NO;adsorption;active carbon;temperature swing adsorption process. Adsorption of NO, especially in the range 0.5-20 ppm, for various adsorbents are studied with adsorption at ambient temperature and with desorption at 353 K. Phenol resin based active carbon is found to have excellent adsorption characteristics and can achieve almost zero emission of NO. It can reach a maximum adsorptivity of 2.5 × 10-3m-3·kg under the presence of O2 for the initial gas concentration of 15 ppm NO. When desorbed at 353 K, NO concentration in the desorbed gas is about five times higher than that of the initial gas. It is concluded that the temperature swing adsorption process is quite appropriate for enrichment of low level NO. Although CO2 has no adverse effect on the adsorption characteristics, water vapor exerts considerable deleterious effect. Thus it is required to remove water vapor before processing.

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