Enhanced Molecular-Shape Selectivity for Polyaromatic Hydrocarbons through Isotropic-to-Crystalline Phase Transition of Poly(octadecyl acrylate)
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We report temperature-triggered enhancement of molecular-shape selectivity by poly(octadecyl acrylate) which undergoes isotropic-to-crystalline phase transition. In this communication, it is also proposed that π–π interaction is included in this selective interaction and is enhanced through orientation of the carbonyl groups which are in a crystalline state.
- Chemistry Letters
Chemistry Letters 2001(12), 1252-1253, 2001-12-05
The Chemical Society of Japan