Synthesis and Fluorescence Emission Behavior of <i>anti</i>-[2.3](3,10)Phenanthrenophane: Overlap between Phenanthrene Rings Required for Excimer Formation

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<jats:title>Abstract</jats:title> <jats:p>Novel anti-[2.3](3,10)phenanthrenophane 3, prepared by the intramolecular [2 + 2] photocycloaddition of 1,3-bis(3-vinyl-10-phenanthryl)propane, exhibited monomer fluorescence. This is in a remarkable contrast with the excimer fluorescence emission from anti-[2.3](3,9)phenanthrenophane 2 with slightly larger overlap between phenanthrene rings than in anti-3.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 30 (10), 970-971, 2001-10-01

    Oxford University Press (OUP)

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