Synthesis of Galactosyl Maltooligosyl β-Cyclodextrins by Condensation Reaction of Debranching Enzymes

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  • 枝切り酵素の縮合反応によるガラクトシルマルトオリゴシルβ-サイクロデキストリンの合成
  • エダギリ コウソ ノ シュクゴウ ハンノウ ニヨル ガラクトシルマルトオリゴシ

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Abstract

The condensation reaction of β-cyclodextrin (βCD) and galactosyl-maltooligosaccharides (4-O-β-D-galactopyranosyl-maltooligosaccharides) was investigated using pullulanase and isoamylase. The structures of the condensation products were found to be β-D-galactosyl-(1→4)-α-maltosyl-(1→6)-βCD, β-D-galactosyl-(1→4)-α-maltotriosyl-(1→6)-βCD, β-D-galactosyl-(1→4)-α-maltotetraosyl-(1→6)-βCD and β-n-galactosyl-(1→4)-α-maltopentaosyl-(1→6)-βCD by FABMS, 13C-NMR and methylation analysis.

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