海水中の有価金属を高度に認識する抽出試薬 : カリックスアレーン化合物  [in Japanese] Novel Extractants with High Selectivity for Valuable Metals in Seawater : Calixarene Derivatives  [in Japanese]

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Author(s)

    • 栫 隆彦 KAKOI Takahiko
    • 九州大学工学部応用物質化学科 Department of Chemical Science and Technology, Faculty of Engineering, Kyushu University
    • 後藤 雅宏 GOTO Masahiro
    • 九州大学工学部応用物質化学科 Department of Chemical Science and Technology, Faculty of Engineering, Kyushu University

Abstract

Seawater contains various valuable metals such as uranium and lithium. Therefore, attempts are being made to develop highly selective extractants which recognize target metal ions in reclaimed seawater. In this review, we have focused our study on the application of novel cyclic compound calixarene based extractants. A novel host compound calixarene, which is a cyclic compound connecting some phenol rings, is capable of forming several different extractant ring sizes and introducing various kinds of functional groups towards targeting of metal ions in seawater. Therefore, calixarene derivatives are capable of extracting valuable metals such as uranium, alkaline metals, heavy metals, rare earth metals and noble metals selectively by varying structural ring size and functional groups. The novel host compound calixarene has given promising results which line it up as a potential extractant for the separation of valuable metal ions in seawater.

Journal

  • Bulletin of the Society of Sea Water Science, Japan

    Bulletin of the Society of Sea Water Science, Japan 51(5), 319-324, 1997-10-01

    The Society of Sea Water Science, Japan

References:  32

  • <no title>

    ZINKE A.

    Chem. Ber. 77, 264, 1944

    Cited by (1)

  • <no title>

    KAMMERER H.

    Die Makromol. Chem. 162, 179, 1972

    Cited by (1)

  • <no title>

    GUTSCHE C. D.

    Acc. Chem. Res. 16, 161, 1983

    Cited by (11)

  • <no title>

    GUTSCHE C. D.

    J. Am. Chem. Soc. 103, 3782, 1981

    Cited by (6)

  • <no title>

    UNGARO R.

    J. Incl. Phenom. 2, 199, 1984

    Cited by (2)

  • <no title>

    SHINKAI S.

    J. Chem. Soc. Perkin Trans. 2, 1167, 1989

    Cited by (2)

  • <no title>

    SHINKAI S.

    Bull. Chem. Soc. Jpn. 62, 4055, 1989

    Cited by (4)

  • <no title>

    NAGASAKI T.

    J. Chem. Soc. Perkin Trans. 2, 1063, 1991

    Cited by (2)

  • <no title>

    ARAKI K.

    Chem. Lett. 829, 1993

    Cited by (2)

  • <no title>

    ARNAUD-NEU F.

    J. Chem. Soc., Perkin Trans. 2, 1175, 1996

    Cited by (1)

  • <no title>

    IZATT R. M.

    J. Am. Chem. Soc. 105, 1782, 1983

    Cited by (12)

  • <no title>

    IZATT S. R.

    J. Am. Chem. Soc. 107, 63, 1985

    Cited by (6)

  • <no title>

    CHANG S. -K.

    J. Chem. Soc. Perkin Trans. 1, 211, 1986

    Cited by (2)

  • <no title>

    CHANG S. -K.

    Chem. Lett. 947, 1987

    Cited by (1)

  • <no title>

    ARIMURA T.

    Bull. Chem. Soc. Jpn. 62, 1674, 1989

    Cited by (5)

  • <no title>

    ARDUINI A.

    Tetrahedron 42, 2089, 1986

    Cited by (7)

  • <no title>

    DENG G.

    Chem. Lett. 1287, 1992

    Cited by (1)

  • <no title>

    OGATA M.

    J. Am. Chem. Soc. 116, 4505, 1994

    Cited by (7)

  • <no title>

    CASNATI A.

    J. Am. Chem. Soc. 117, 2767, 1995

    Cited by (3)

  • <no title>

    YAMAMOTO H.

    Chem. Lett. 497, 1995

    Cited by (1)

  • <no title>

    HAMADA F.

    J. Incl. Phenom. Mol. Recog. Chem. 10, 57, 1991

    Cited by (1)

  • <no title>

    NAGASAKI T.

    Bull. Chem. Soc. Jpn. 65, 471, 1992

    Cited by (5)

  • <no title>

    DELIGOZ H.

    Solv. Extr. Ion Exch. 13, 19, 1995

    Cited by (1)

  • <no title>

    OHTO K.

    Solv. Extr. Ion Exch. 14, 459, 1996

    Cited by (2)

  • <no title>

    LUDWIG R.

    Solv. Extr. Ion Exch. 11, 311, 1993

    Cited by (2)

  • <no title>

    OHTO K.

    Anal. Sci. 11, 893, 1995

    Cited by (10)

  • <no title>

    OHTO K.

    Polyhedron 16, 1655, 1997

    Cited by (6)

  • <no title>

    OHTO K.

    Solv. Extr. Res. Dev., Jpn. 4, 167, 1997

    Cited by (2)

  • <no title>

    OHTO K.

    Anal. Chim. Acta 17863, 1, 1997

    Cited by (1)

  • <no title>

    KOH K. N.

    Tetrahedron Lett. 35, 4157, 1994

    Cited by (2)

  • <no title>

    YORDANOV A. T.

    New J. Chem. 20, 447, 1996

    Cited by (1)

  • <no title>

    NAGASAKI T.

    J. Chem. Soc. Perkin Trans. 1, 2617, 1990

    DOI  Cited by (2)

Codes

  • NII Article ID (NAID)
    10008281209
  • NII NACSIS-CAT ID (NCID)
    AN0018645X
  • Text Lang
    JPN
  • Article Type
    REV
  • ISSN
    03694550
  • NDL Article ID
    4313289
  • NDL Source Classification
    ZM44(科学技術--地球科学--海洋・陸水・火山) // ZP8(科学技術--化学・化学工業--無機化学・無機化学工業)
  • NDL Call No.
    Z15-47
  • Data Source
    CJP  NDL  J-STAGE 
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