Syntheses of Novel Net-worked Hybrid Copolymers with Alternative Tantalum-Organic Moieties

  • KUDO Ryoichi
    Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
  • MATSUI Hideo
    Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
  • YOSHIHARA Masakuni
    Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University Molecular Engineering Institute, Kinki University

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  • タンタル-有機基交互構造を有する新規ハイブリッド共重合体の合成
  • タンタルー ユウキキ コウゴ コウゾウ オ ユウスル シンキ ハイブリッド キョウジュウゴウタイ ノ ゴウセイ

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Abstract

The reactions of tantalum butoxide with several organic diols gave novel net-worked alternative tantalum-organic moieties hybrid copolymers particles whose forms and sizes varied with the organic units. Electron transfer from aromatic groups to tantalum atom in the net-worked structures was demonstrated by the results of ESR spectra and ab-initio calculations.

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