Time- and Frequency-resolved Photoelectrochemical Investigations on Nano-honeycomb TiO2 Electrodes

DOI Web Site Web Site 被引用文献4件 参考文献37件
  • YOSHIDA Tsukasa
    Environmental and Renewable Energy Systems Division, Graduate School of Engineering, Gifu University
  • SHINADA Atsushi
    Environmental and Renewable Energy Systems Division, Graduate School of Engineering, Gifu University
  • OEKERMANN Torsten
    Environmental and Renewable Energy Systems Division, Graduate School of Engineering, Gifu University
  • SUGIURA Takashi
    Environmental and Renewable Energy Systems Division, Graduate School of Engineering, Gifu University
  • SAKAI Tatsuya
    Environmental and Renewable Energy Systems Division, Graduate School of Engineering, Gifu University
  • MINOURA Hideki
    Environmental and Renewable Energy Systems Division, Graduate School of Engineering, Gifu University

書誌事項

タイトル別名
  • Time- and Frequency-resolved Photoelectrochemical Investigations on Nano-honeycomb TiO<sub>2</sub> Electrodes

この論文をさがす

抄録

<p>Time- and frequency-resolved photoelectrochemical studies have been performed on nano-honeycomb porous TiO2 electrode prepared by photoelectrochemical etching of single crystal TiO2, both for its bare surface and when sensitized by cis-di(thiocyanato)-N,N-bis(2,2’-bipyridyl-4,4’-dicalboxylate)ruthenium(II). Since the remaining wall in the porous layer become as thin as the double thickness of the space charge layer by photoetching, electron diffusion comes to play the main role in the charge transport rather than field-driven migration. Intensity modulated photocurrent spectroscopy revealed much faster electron diffusion in the honeycomb electrode than that in colloid based porous electrode, because of the smaller electron trap density in the nano-honeycomb structure owing to the nonexistence of grain boundaries.</p>

収録刊行物

  • Electrochemistry

    Electrochemistry 70 (6), 453-456, 2002-06-05

    公益社団法人　電気化学会

被引用文献 (4)*注記

もっと見る

参考文献 (37)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ