高分子荷電膜の輸送現象  [in Japanese] Transport Properties of Ionomer Membranes for Polymer Electrolyte Fuel Cells  [in Japanese]

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Author(s)

    • 岡田 達弘 OKADA Tatsuhiro
    • 産業技術総合研究所 環境調和技術研究部門 Institute for Green Technology, National Institute of Advanced Industrial Science and Technology

Abstract

Water and ion transport characteristics are discussed with relevance to the microscopic structural properties of perfluorinated ionomer membranes that are used as H<SUP>+</SUP> conducting membranes in polymer electrolyte fuel cells. Some morphological models of ion pair aggregation and cluster formation are briefly introduced, together with reported experimental results like diffraction or spectroscopic studies. Transport models in the ionomer membranes are also discussed that can fit the experimental data. A new concept of ion transport in the polymer membrane in relation to the interaction of ion and water molecules inside the ionic channel is proposed, which is to become of particular use in designing high performance ion conducting polymer membranes.

Journal

  • MEMBRANE

    MEMBRANE 27(3), 108-117, 2002-05-01

    THE MEMBRANE SOCIETY OF JAPAN

References:  32

  • <no title>

    EISENBERG A.

    "Perfluorinated lonomer Membranes" ACS Symposium series 180, 1982

    Cited by (1)

  • <no title>

    PINERI M.

    "Structure and Properties of Ionomers" NATO ASI Series C, 1986

    Cited by (1)

  • <no title>

    TANT MR.

    Ionomers, 1997

    Cited by (1)

  • <no title>

    神原周

    高分子電解質(高分子実験学13), 1978

    Cited by (1)

  • <no title>

    GRAY M.

    Solid Polymer Electrolyte, 1991

    Cited by (1)

  • <no title>

    小山昇

    新型電池の材料科学(季刊化学総説No. 49), 2001

    Cited by (1)

  • <no title>

    EISENBERG A.

    Macromolecules 3, 147, 1970

    Cited by (12)

  • <no title>

    GIERKE T. D.

    J. Polym. Sci. 19, 1687, 1981

    Cited by (6)

  • <no title>

    HSU W.

    J. Membrane Sci. 13, 307, 1983

    Cited by (1)

  • <no title>

    MOORE RB.

    Macromolecules 22, 3594, 1989

    Cited by (1)

  • <no title>

    FALK M.

    Can. J. Chem. 58, 1495, 1980

    Cited by (4)

  • <no title>

    LOWRY SR.

    J. Am. Chem. Soc. 102, 4665, 1980

    Cited by (8)

  • <no title>

    LAPORTA M.

    Phys. Chem. Chem. Phys. 1, 4619, 1999

    Cited by (1)

  • <no title>

    YEAGER H. L.

    J. Electrochem. Soc. 128, 1880, 1981

    Cited by (3)

  • <no title>

    MACKIE JS.

    Proc. Roy. Soc., Ser. A 232, 498, 1955

    Cited by (2)

  • <no title>

    YASUDA H.

    Macromol. Chem. 118, 19, 1968

    Cited by (1)

  • <no title>

    ZAWODZINSKI Jr.

    J. Electrochem. Soc. 140, 1981, 1993

    Cited by (1)

  • <no title>

    OKADA T.

    Electrochim. Acta 43, 3741, 1998

    Cited by (1)

  • <no title>

    XIE G.

    J. Chem. Soc., Faraday Trans. 92, 663, 1996

    Cited by (1)

  • <no title>

    YANG Y.

    AIChE Journal 46, 1177, 2000

    Cited by (1)

  • <no title>

    PADDISON SJ.

    J. Electrochem. Soc. 147, 617, 2000

    Cited by (1)

  • <no title>

    STECK A.

    Anal. Chem. 52, 1215, 1980

    Cited by (1)

  • <no title>

    岡田達弘

    表面 39, 51, 2001

    Cited by (1)

  • <no title>

    XIE G.

    Denki Kagaku 64, 718, 1996

    Cited by (1)

  • <no title>

    SAMEC Z.

    J. Phys. Chem. 98, 6352, 1994

    Cited by (1)

  • <no title>

    OKADA T.

    J. Phys. Chem, B 103, 3315, 1999

    Cited by (2)

  • <no title>

    OKADA T.

    J. Phys. Chem, B 106, 1267, 2002

    Cited by (1)

  • <no title>

    大瀧仁志

    イオンの水和(化学One Point 26), 1995

    Cited by (1)

  • <no title>

    有村菜穂子

    電気化学会第69回大会予稿集 3C03, 2002

    Cited by (1)

  • <no title>

    NEDO成果報告書H11:固体高分子型燃料電池の研究開発, 2000

    Cited by (1)

  • <no title>

    HEITNER-WIRGUIN C.

    J. Membr. Sci. 120, 1, 1996

    DOI  Cited by (4)

  • <no title>

    PINTAURO PN.

    J. Phys. Chem. 99, 12915, 1995

    DOI  Cited by (1)

Codes

  • NII Article ID (NAID)
    10008588832
  • NII NACSIS-CAT ID (NCID)
    AN0023215X
  • Text Lang
    JPN
  • Article Type
    REV
  • ISSN
    03851036
  • NDL Article ID
    6152274
  • NDL Source Classification
    ZR2(科学技術--生物学--生化学)
  • NDL Call No.
    Z18-1127
  • Data Source
    CJP  NDL  J-STAGE 
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