サマリウム化合物を触媒とする合成反応の開発  [in Japanese] Development of New Synthetic Reactions Using Samarium Compounds as Catalysts  [in Japanese]

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Author(s)

    • 西山 豊 NISHIYAMA Yutaka
    • 関西大学工学部応用化学科 Department of Applied Chemistry, Faculty of Engineering & High Technology Research Center, Kansai University
    • 坂ロ 聡 SAKAGUCHI Satoshi
    • 関西大学工学部応用化学科 Department of Applied Chemistry, Faculty of Engineering & High Technology Research Center, Kansai University
    • 石井 康敬 ISHII Yasutaka
    • 関西大学工学部応用化学科 Department of Applied Chemistry, Faculty of Engineering & High Technology Research Center, Kansai University

Abstract

The utilization of lanthanide metal salts and organolanthanide compounds in organic synthesis has been attracted considerable attention, however, there have been a limited number of studies on the synthetic reactions using divalent samarium compounds such as SmI<SUB>2</SUB> and Cp<SUP>*</SUP><SUB>2</SUB>Sm (thf) <SUB>2</SUB> as catalysts or catalyst precursors. We report here several synthetic reactions by the use of samarium complexes (II), namely SmI<SUB>2</SUB> and Cp<SUP>*</SUP><SUB>2</SUB>Sm (thf) <SUB>2</SUB>, as catalysts : (i) coupling reaction of vinyl esters with aldehydes, (ii) acylation of alcohols and amines with vinyl esters, (iii) acylation of tertiary alcohols with vinyl esters in the presence of a catalytic amount of oxime ester, (iv) synthesis of 1, 3-diol monoesters by the trimerization of aldehydes, (v) aldol type condensation of imines, and (vi) one-pot synthesis of pyrroles by the reaction of amines, aldehydes, and nitroalkanes.

Journal

  • Journal of Synthetic Organic Chemistry, Japan

    Journal of Synthetic Organic Chemistry, Japan 58(2), 129-137, 2000-02-01

    The Society of Synthetic Organic Chemistry, Japan

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Codes

  • NII Article ID (NAID)
    10008819134
  • NII NACSIS-CAT ID (NCID)
    AN0024521X
  • Text Lang
    JPN
  • Article Type
    ART
  • ISSN
    00379980
  • NDL Article ID
    4987417
  • NDL Source Classification
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL Call No.
    Z17-256
  • Data Source
    CJP  NDL  J-STAGE 
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