電気化学的手法によるニッケルの活性化とその有機反応への利用  [in Japanese] Electrochemical Generation of Highly Reactive Nickel and Its Utilization for Organic Reactions  [in Japanese]

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Author(s)

Abstract

A highly reactive nickel powder like Rieke's nickel can be prepared by electrolysis of a DMF solution containing 0.3 mol·dm<SUP>-3</SUP> Bu<SUB>4</SUB>NBF<SUB>4</SUB> or 0.3 mol·dm<SUP>-3</SUP> Et<SUB>4</SUB>NBF<SUB>4</SUB> in an undivided cell with a platinum cathode and a nickel anode without massive deposition onto the cathode at a constant current of 10 mA/cm<SUP>2</SUP> at 0 °C under an argon atmosphere. The transmission electron micrograph of the electrochemically generated nickel powder shows the particle size to be 2-3 nm. The Ullmann-type reaction of aryl halides with the reactive nickel proceeded with approximately the same yields as those using Rieke's metal. Therefore, the electrochemically generated nickel powder has enough activity for reduction of nitrobenzenes and deallylation of allyl aryl ethers. These reactions proceeded without affecting various functional groups at room temperature in a short reaction time.

Journal

  • Journal of Synthetic Organic Chemistry, Japan

    Journal of Synthetic Organic Chemistry, Japan 58(3), 192-198, 2000-03-01

    The Society of Synthetic Organic Chemistry, Japan

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Codes

  • NII Article ID (NAID)
    10008819330
  • NII NACSIS-CAT ID (NCID)
    AN0024521X
  • Text Lang
    JPN
  • Article Type
    ART
  • ISSN
    00379980
  • NDL Article ID
    5301704
  • NDL Source Classification
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL Call No.
    Z17-256
  • Data Source
    CJP  NDL  J-STAGE 
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