14族元素間σ結合の開裂を伴う錯体触媒反応と触媒活性種関連錯体の挙動  [in Japanese] Transition Metal Catalysis Involving Cleavages of σ-Bonds between Group 14 Elements and Characterization of Metal Complexes Relevant to the Catalyst Intermediates  [in Japanese]

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Abstract

Some homogeneous transition metal catalysts are highly active to cleave σ-bonds between group 14 elements under mild reaction conditions. Various unsaturated compounds insert into the a-bonds to afford a wide variety of products having the group 14 elements. We have utilized silylstannanes (Si-Sn), disilanes (Si-Si), and distannanes (Sn-Sn) in the presence of a transition metal catalyst to realize 1, 4-silylstannation of 1, 3-dienes, 1, 2-silylstannation of olefins, dimerization and bis-silylation of 1, 3-dienes, 1, 4-carbosilylation of 1, 3-dienes, silylation of allylic esters, and bisstannylation of 1, 3-dienes. The structures and fluxional behavior of <I>cis</I>-bis (stannyl) bis (phosphine) platinum, <I>cis</I>-bis (silyl) bis (phosphine) platinum, and <I>cis</I>-bis (stannyl) bis (phosphine) palladium complexes were examined. In the fluxional process, all the spin-spin couplings are retained. The fluxionality is attributed to unimolecular twist-rotation via a pseudotetrahedral transition state.

Journal

  • Journal of Synthetic Organic Chemistry, Japan

    Journal of Synthetic Organic Chemistry, Japan 58(3), 199-207, 2000-03-01

    The Society of Synthetic Organic Chemistry, Japan

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Codes

  • NII Article ID (NAID)
    10008819374
  • NII NACSIS-CAT ID (NCID)
    AN0024521X
  • Text Lang
    JPN
  • Article Type
    ART
  • ISSN
    00379980
  • NDL Article ID
    5301707
  • NDL Source Classification
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL Call No.
    Z17-256
  • Data Source
    CJP  NDL  J-STAGE 
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