海産藍藻由来魚毒活性物質アンチラトキシンの全合成 Total Synthesis of Antillatoxin, an Ichthyotoxic Cyclic Lipopeptide from Marine Cyanobacterium Lyngbya majuscula

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抄録

Antillatoxin is an ichthyotoxic cyclic lipopeptide isolated by Gerwick and co-workers from the marine cyanobacterium <I>Lyngbya majuscula</I> collected in Curacao. Although we have finished the stereoselective total synthesis of antillatoxin having the proposed structure with (4<I>S</I>, 5<I>R</I>) -configuration, we have found that the synthetic sample was not identical with the natural one and the proposed structure should be revised. Further our synthetic efforts have culminated in the first total synthesis of antillatoxin in its natural form, proving that the natural one has (4<I>R</I>, 5<I>R</I>) -configuration. In this account, our total synthesis and synthetic studies by other groups will be discussed.

収録刊行物

  • 有機合成化学協会誌

    有機合成化学協会誌 58(7), 634-641, 2000-07-01

    The Society of Synthetic Organic Chemistry, Japan

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各種コード

  • NII論文ID(NAID)
    10008820585
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    00379980
  • NDL 記事登録ID
    5397587
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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