パラジウム触媒を用いる不斉マンニッヒ型反応  [in Japanese] Asymmetric Mannich-Type Reaction by Catalyzed Palladium Complexes  [in Japanese]

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Abstract

Carbon-carbon bond-forming reactions that involve the addition of resonance-stabilized nudeophiles, such as enols and enolates, to iminium salts and imines, the so-called Mannich-type reactions, comprise one of the most important classes of reaction in organic synthesis. A number of methods for the diastereoselective reaction of imines with enolates of carboxylic acid derivatives or silyl ketene acetals have been reported, but examples of enantioselective variants of this type of reaction are quite limited. This article briefly reviews recent progress of enantioselective Mannich-type reactions, and describes our studies on the enantioselective addition of enol silyl ethers to imines catalyzed by optically active palladium complexes including its mechanistic aspects.

Journal

  • Journal of Synthetic Organic Chemistry, Japan

    Journal of Synthetic Organic Chemistry, Japan 58(8), 728-735, 2000-08-01

    The Society of Synthetic Organic Chemistry, Japan

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Codes

  • NII Article ID (NAID)
    10008821106
  • NII NACSIS-CAT ID (NCID)
    AN0024521X
  • Text Lang
    JPN
  • Article Type
    Journal Article
  • ISSN
    00379980
  • NDL Article ID
    5431900
  • NDL Source Classification
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL Call No.
    Z17-256
  • Data Source
    CJP  CJPref  NDL  J-STAGE 
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