Alicyclic Polyimides. An Approach from Monomer Synthesis.

• Matsumoto Toshihiko

  Department of Applied Chemistry, Faculty of Engineering, Tokyo Institute of Polytechnics

Bibliographic Information

Other Title

• 脂環式ポリイミド　　モノマー合成からのアプローチ
• シカンシキ ポリィミド モノマー ゴウセイ カラ ノ アプローチ
• <I>An Approach from Monomer Synthesis</I>
• モノマー合成からのアプロチ

Abstract

Polyimides obtained from dianhydrides and diamines by the polycondensation are classified into four distinct categories according to the chemical structure of the monomers. Aliphatic polyimides derived from aliphatic monomers are soluble in organic solvents and form the colorless and flexible films, whereas most of fully aromatic polyimides such as Kapton® are insoluble and absorb visible light. Especially, alicyclic monomer based polyimides have attracted much attention in recent years because of their potential applications including use as liquid crystal orientation layers or low dielectric materials. In this review, a historical aspect and recent advances in the polyimide synthesis are described with particular focus and emphasis on the monomer synthesis using the Diels-Alder reaction, the Pd-catalyzed methoxycarbonylation and so on.

Journal

• Journal of Synthetic Organic Chemistry, Japan

  Journal of Synthetic Organic Chemistry, Japan 58 (8), 776-786, 2000

  The Society of Synthetic Organic Chemistry, Japan

Keywords

• alicyclic polyimides
• aliphatic polyimides
• colorless polyimides
• monomer synthesis
• Diels-Alder reaction
• Pd-catalyzed methoxycarbonylation
• liquid crystal orientation layer
• low dielectric materials

Details

• CRID: 1390282680255788928
• NII Article ID: 10008821389
• NII Book ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.58.776
• COI: 1:CAS:528:DC%2BD3cXls1ehurs%3D
• ISSN: 18836526
• ISSN: 00379980
• NDL BIB ID: 5432052
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5432052
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed