均一系ルテニウム錯体触媒を用いるγ-ブチロラクトンの新規製造法  [in Japanese] A Novel Production of γ-Butyrolactone Catalyzed by Homogeneous Ruthenium Complexes  [in Japanese]

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Author(s)

Abstract

γ-Butyrolactone (GBL) is produced by a two-stage hydrogenation of maleic anhydride (MAH) in the liquid phase : a hydrogenation of MAH to succinic anhydride (SAH) in the first stage and a subsequent hydrogenation of SAH to GBL in the second stage. A novel ruthenium catalyst system consisting of Ru salts, trialkylphosphine and <I>p</I>-toluenesulfonic acid (<I>p</I>-TsOH) was found very effective for the hydrogenation of SAH affording GBL in selectivities not less than 95%. Acid promoters like p-TsOH induce structural change in the Ru complexes, leading to the cationic complexes, which show higher catalytic activity and selectivity than the neutral ones. A new process to produce GBL was also developed, in which the features are external preparation of Ru complexes, the reaction protocol which combine over-flow reaction with stripping and the catalyst recovery system by the extraction.

Journal

  • Journal of Synthetic Organic Chemistry, Japan

    Journal of Synthetic Organic Chemistry, Japan 58(8), 787-794, 2000-08-01

    The Society of Synthetic Organic Chemistry, Japan

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Codes

  • NII Article ID (NAID)
    10008821495
  • NII NACSIS-CAT ID (NCID)
    AN0024521X
  • Text Lang
    JPN
  • Article Type
    OTR
  • ISSN
    00379980
  • NDL Article ID
    5432062
  • NDL Source Classification
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL Call No.
    Z17-256
  • Data Source
    CJP  NDL  J-STAGE 
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