Isomerization of Oxygen-substituted Cyclopropanes by Metal Catalysis.

• Sugimura Takashi

  the Faculty of Science, Himeji Institute of Technology

• Ryu Ilhyong

  Department of Chemistry, Faculty of Arts and Sciences, Osaka Prefecture University,

抄録

Highly regio- and stereospecific isomerization reactions of siloxy- and alkoxycyclopropanes were effected under mild reaction conditions by a variety of metal-catalyzed systems using such as Zn (II), Pt (II), Rh (I), and Ni (0). It is noteworthy that the conversion of siloxycyclopropanes to allyl silyl ethers was established by the use of either zinc iodide or Zeise's dimer. The scope, limitations, and mechanisms of isomerization of siloxy- and alkoxy-substituted cyclopropanes are discussed.

収録刊行物

• 有機合成化学協会誌

  有機合成化学協会誌 58 (11), 1100-1107, 2000

  公益社団法人 有機合成化学協会

キーワード

• Organic Chemistry

詳細情報

• CRID: 1390282680256003584
• NII論文ID: 10008822354
• NII書誌ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.58.1100
• ISSN: 18836526
• ISSN: 00379980
• NDL書誌ID: 5549735
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5549735
• 本文言語コード: en
• データソース種別:
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• 抄録ライセンスフラグ: 使用不可