Isomerization of Oxygen-substiuted Cyclopropanes by Metal Catalysis

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Abstract

Highly regio- and stereospecific isomerization reactions of siloxy- and alkoxycyclopropanes were effected under mild reaction conditions by a variety of metal-catalyzed systems using such as Zn (II), Pt (II), Rh (I), and Ni (0). It is noteworthy that the conversion of siloxycyclopropanes to allyl silyl ethers was established by the use of either zinc iodide or Zeise's dimer. The scope, limitations, and mechanisms of isomerization of siloxy- and alkoxy-substituted cyclopropanes are discussed.

Journal

  • Journal of Synthetic Organic Chemistry, Japan

    Journal of Synthetic Organic Chemistry, Japan 58(11), 110-1107, 2000-11-01

    The Society of Synthetic Organic Chemistry, Japan

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Codes

  • NII Article ID (NAID)
    10008822354
  • NII NACSIS-CAT ID (NCID)
    AN0024521X
  • Text Lang
    ENG
  • Article Type
    REV
  • ISSN
    00379980
  • NDL Article ID
    5549735
  • NDL Source Classification
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL Call No.
    Z17-256
  • Data Source
    CJP  NDL  J-STAGE 
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