シロキサン・シラノールの有機化学  [in Japanese] Organic Chemistry of Siloxane and Silanol  [in Japanese]

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Abstract

This article reviews organic chemistry of siloxane and silanol involving the preparative method as well as applications towards organic synthesis. Chapter 1 deals with the formation of siloxane bond and reactions of thus prepared siloxane compounds. Chapter 2 covers recent preparative methods for silanols and new synthetic reaction using silanol involving 1) utilization of silanol oxygen that serves as a base or a nucleophile, 2) transformation of neighboring functionality on the silicon substituent based on the interaction of silanol oxygen with an organometallic reagent, and 3) transformation of a carbon silicon bond of silanols directed to novel carbon-carbon bond forming reactions.

Journal

  • Journal of Synthetic Organic Chemistry, Japan

    Journal of Synthetic Organic Chemistry, Japan 58(10), 926-933, 2000-10-01

    The Society of Synthetic Organic Chemistry, Japan

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Codes

  • NII Article ID (NAID)
    10008823905
  • NII NACSIS-CAT ID (NCID)
    AN0024521X
  • Text Lang
    JPN
  • Article Type
    Journal Article
  • ISSN
    00379980
  • NDL Article ID
    5512262
  • NDL Source Classification
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL Call No.
    Z17-256
  • Data Source
    CJP  CJPref  NDL  J-STAGE 
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