希土類イオンの有機媒体発光:ネオジム錯体の配位子設計とその展開  [in Japanese] Luminescence of Neodymium(III) in Organic Media : Ligand Designs for the Remarkable Luminescence and Their Evolution  [in Japanese]

Access this Article

Search this Article

Author(s)

    • 柳田 祥三 YANAGIDA Shozo
    • 大阪大学大学院工学研究科物質・生命工学専攻 Material and Life Sicence, Graduate School of Engineering, Osaka University
    • 和田 雄二 WADA Yuji
    • 大阪大学大学院工学研究科物質・生命工学専攻 Material and Life Sicence, Graduate School of Engineering, Osaka University

Abstract

The relatively low efficiency of Nd (III) emission in organic media has been improved by 1) suppression of the radiationless transition process via vibrational excitation of the surrounding medium, 2) prevention of dipole-dipole nonradiative energy transfer processes via energy migration, 3) suppression of radiationless transition of D<SUB>2</SUB>O molecules in the vicinity of Nd (III) complexes (formation of twelve-coordinate Nd (III) complex with DMSO-<I>d</I><SUB>6</SUB>), 4) allowance of electron transitions of Nd (III) by the introduction of asymmetric ligand field, 5) photosensitization by use of energy transfer from organic ligands. The luminescence of NMI) was observed for the first time in undeuterated acetone when Nd (III) was complexed with bis-perfluorooctylsulfonylamine (pos). As to the applications of luminescent Nd (III) complexes, developments of luminescent lanthanide polymers and EL device were successful.

Journal

  • Journal of Synthetic Organic Chemistry, Japan

    Journal of Synthetic Organic Chemistry, Japan 58(10), 945-955, 2000-10-01

    The Society of Synthetic Organic Chemistry, Japan

References:  28

  • <no title>

    足立吟也

    希土類の科学, 1999

    Cited by (7)

  • <no title>

    STRUCK C. W.

    Advances in Nonradiative Processes in Solid, 63-132, 1991

    Cited by (1)

  • <no title>

    GAN F.

    LASER MATERIALS, 1995

    Cited by (4)

  • <no title>

    ZELLMER H.

    Optics Lett. 20, 578, 1995

    Cited by (2)

  • <no title>

    LIU A.

    Optics Communications 132, 511, 1996

    Cited by (2)

  • <no title>

    RICHARD J. K.

    Nature 393, 769, 1998

    Cited by (2)

  • <no title>

    BEEDY A.

    Chem. Phys. Lett. 266, 116, 1996

    Cited by (1)

  • <no title>

    HASEGAWA Y.

    Chem. Phys. Lett. 248, 8, 1996

    Cited by (11)

  • <no title>

    YANAGIDA S.

    Coord. Chem. Rev. 171, 461, 1998

    Cited by (8)

  • <no title>

    柳田祥三

    光化学 26, 22, 1997

    Cited by (2)

  • <no title>

    柳田祥三

    科学と工業 72, 333, 1998

    Cited by (2)

  • <no title>

    長谷川靖哉

    化学と工業 53, 126, 2000

    Cited by (3)

  • <no title>

    HASEGAWA Y.

    Chem. Phys. Lett. 260, 173, 1996

    Cited by (9)

  • <no title>

    HASEGAWA Y.

    J. Phys. Chem. 100, 10201, 1996

    Cited by (10)

  • <no title>

    HASEGAWA Y.

    BULL. Chem. Soc. Jpn 71, 2573, 1998

    Cited by (6)

  • <no title>

    IWAMURO M.

    J. Lumin. 79, 29, 1998

    Cited by (7)

  • <no title>

    IWAMURO M.

    Chem.Lett. 1999, 539

    Cited by (5)

  • <no title>

    HASEGAWA Y.

    Angew. Chem. Int. Ed. 39, 357, 2000

    Cited by (4)

  • <no title>

    ARNAUD R.

    J. Phys. Chem. 100, 10882, 1996

    Cited by (1)

  • <no title>

    FOROPOULOS J.

    Inorg. Chem. 23, 3720, 1984

    Cited by (4)

  • <no title>

    KOBAYASHI H.

    Chem. Lett. 1995, 307

    Cited by (6)

  • <no title>

    SOGABE K.

    Chem. Lett. 2000, 944

    Cited by (1)

  • <no title>

    HASEGAWA Y.

    Chem. Lett. 1999, 35

    Cited by (3)

  • <no title>

    KAWAMURA Y.

    Appl. Phys. Lett. 74, 3245, 1999

    Cited by (8)

  • <no title>

    TANG C. W.

    Appl. Phys. Lett. 51, 913, 1987

    Cited by (290)

  • <no title>

    FUKUZUMI S.

    Advances in Photochemistry 25, 107, 1999

    Cited by (1)

  • <no title>

    BORGMANN C.

    Adv. Mater. 11, 45, 1999

    Cited by (4)

  • <no title>

    YANAGIDA S.

    J. Lumin. 87-89, 995, 2000

    DOI  Cited by (3)

Codes

  • NII Article ID (NAID)
    10008824028
  • NII NACSIS-CAT ID (NCID)
    AN0024521X
  • Text Lang
    JPN
  • Article Type
    ART
  • ISSN
    00379980
  • NDL Article ID
    5512281
  • NDL Source Classification
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL Call No.
    Z17-256
  • Data Source
    CJP  NDL  J-STAGE 
Page Top