機能性カルバニオン「イノラートアニオン」の合成と反応  [in Japanese] Syntheses and Reactions of Multifunctional Carbanions "Ynolate Anions"  [in Japanese]

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Author(s)

    • 新藤 充 SHINDO Mitsuru
    • 徳島大学薬学部附属医薬資源教育研究センター Institute for Medicinal Resources, University of Tokushima

Abstract

Ynolates are carbanions having a triple bond in place of the double bond in enolate anions. Ynolates are ketene anion equivalents, thus ynolates introduce a ketene unit into substrates and the resulting products possess high reactivity. This allows ynolates to undergo unique reaction sequences. For the past 20 years, several methods for the generation of ynolates and their reactions have been developed. Recently, we have developed a highly efficient method for their generation and new rections such as olefination, tandem [2+2] cycloaddition-Dieckmann condensation, syntheses of β-lactams. In this review, an overview of the syntheses and the reactions of ynolates, especially focusing our recent results, are described.

Journal

  • Journal of Synthetic Organic Chemistry, Japan

    Journal of Synthetic Organic Chemistry, Japan 58(12), 1155-1166, 2000-12-01

    The Society of Synthetic Organic Chemistry, Japan

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Codes

  • NII Article ID (NAID)
    10008824458
  • NII NACSIS-CAT ID (NCID)
    AN0024521X
  • Text Lang
    JPN
  • Article Type
    Journal Article
  • ISSN
    00379980
  • NDL Article ID
    5593964
  • NDL Source Classification
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL Call No.
    Z17-256
  • Data Source
    CJP  CJPref  NDL  J-STAGE 
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