Fabrication of HTSC Single Crystalline Thin Films by Tri-Phase Epitaxy

  • Takahashi Ryota
    Frontier Collaborative Research Center, Tokyo Institute of Technology
  • Yun Kyung Sung
    Frontier Collaborative Research Center, Tokyo Institute of Technology
  • Matsumoto Yuji
    Materials and Structures Laboratory, Tokyo Institute of Technology
  • Kawasaki M.
    Department of Innovative and Engineered Materials, Tokyo Institute of Technology Institute of Material Research, Tohoku University Combinatorial Materials Exploration and Technology
  • Chikyow Toyohiro
    National Institute for Materials Science Combinatorial Materials Exploration and Technology
  • Koinuma Hideomi
    Frontier Collaborative Research Center, Tokyo Institute of Technology Materials and Structures Laboratory, Tokyo Institute of Technology Combinatorial Materials Exploration and Technology CREST-Japan Science Technology Corporation

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  • Tri-Phase Epitaxyによる高温超伝導,単結晶薄膜の作製
  • Tri Phase Epitaxy ニ ヨル コウオン チョウデンドウ タンケッショウ ハクマク ノ サクセイ

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Abstract

A high-Tc superconducting (HTSC) thin film with single crystal quality and atomically flat surface is a basic requirement for the fabrication of HTSC electronic devices. Despite extensive effort since the discovery of high-Tc superconductivity, this requirement has not been fully satisfied yet. Based on our experience on HTSC thin film growth, we proposed a novel fabricating method of single crystal RBa2Cu3O7−δ(R=Y, Nd) thin films that are free from grain boundaries and have atomic scale surface smoothness. This method was devised in view of the thermodynamic phase diagram of RBa2Cu3O7−δ and the characteristics of vapor phase epitaxy (VPE). Since gas, liquid and solid phases are involved in this film growth, it is denoted Tri-Phase Epitaxy(TPE). Giant single crystal grains, verified by X-ray diffraction and transmission electron microscopy (TEM), should provide a big advantage for the use of these films in such applications as high frequency transmission lines and superconducting tunnel junctions.

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