Melt-Growth Joining of Superconductive YBCO Crystals with YBCO/Ag Insert

  • Kuroki Takashi
    Department of Materials Process Engineering, Graduate School of Engineering, Kyushu University
  • Mori Nobuyuki
    Department of Materials Science and Engineering, Faculty of Engineering, Kyushu University
  • Ogi Keisaku
    Department of Materials Science and Engineering, Faculty of Engineering, Kyushu University

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Other Title
  • 超伝導YBCO結晶のYBCO/Agによる溶融凝固接合
  • チョウデンドウ YBCO ケッショウ ノ YBCO Ag ニ ヨル ヨウユウ ギョウコ セツゴウ

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Abstract

Melt/growth mechanism and interfacial reaction of YBCO superconductive oxide with molten Ag and YBCO/Ag composite were analyzed to clarify the best fabricating condition of YBCO crystals junction.<BR>The peritectic temperature of YBCO(liquid+Y2BaCuO5(Y211)→YBa2Cu3O7−x(Y123)) was lowered toward 1242(±2) K from 1280 K by the addition of Ag, and Y123 phase dissolved into liquid(containing Ag+)+Y211 phases above 1244 K. Therefore Ag and YBCO/Ag composites were used as the inserted low-melting point materials for Y123 crystals. The surface layer of YBCO crystal was melted due to Ag diffusion from inserted YBCO/Ag into the crystals. By cooling the joint under 1240 K, Y123 crystals developed from base YBCO and a superconductive joint was obtained.<BR>It was clarified that Ag diffuses from inserted YBCO/Ag composite into YBCO crystals mainly along Y123-Y211 boundaries.

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