Allenyl(vinyl)methane Photochemistry. Photochemistry of 5-[2-(1,2-Propadienyl)-Substituted Alkylidene]-2,2-dimethyl-1,3-dioxane-4,6-diones
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- Takashi Tsuno
- Department of Industrial Chemistry, College of Industrial Technology, Nihon UniversityNarashino, Chiba 275
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- Kunio Sugiyama
- Department of Industrial Chemistry, College of Industrial Technology, Nihon UniversityNarashino, Chiba 275
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<jats:title>Abstract</jats:title> <jats:p>The Photochemistry of 5-[2-(1,2-propadienyl)-substituted alkylidene]-2,2-dimethyl-1,3-dioxane-4,6-diones has been studied. These acylals formed an intramolecular charge-transfer (CT) complex between the 1,2-propadienyl and vinyl moieties in acetonitrile and in hexane, the direct photolyses of which gave (1-alkenylidene)cyclopropanes as the main products, and the intramolecular [2+2] cycloadducts, 3-alkylidene-2′,2′,5,5-tetramethylspiro[bicyclo[2.1.0]pentane-2,5′-[1,3]dioxane]-4′,6′-diones as minor products. The (1-alkenylidene)cyclopropanes were produced from the enol intermediate via a preferred 1,5-hydrogen transfer of a diradical, which was formed via an intramolecular CT excited state. On the other hand, the acetone-sensitized photolyses afforded mainly the intramolecular [2+2] cycloadducts. It is considered that the lowest triplet energies of these acylals in acetonitrile were estimated to lie in the range of 250—290 kJ mol−1, and that these energies were near to the values of the reported triplet energies of α,β-unsaturated esters, because the allene underwent a [2+2] cycloaddition to the triplet vinyl moiety, excited by triplet sensitization.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 68 (11), 3175-3188, 1995-11-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360002219104203136
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- NII論文ID
- 10008895185
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- NII書誌ID
- AA00580132
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- ISSN
- 13480634
- 00092673
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