Alcoholysis of Epoxides Catalyzed by Tetracyanoethylene and Dicyanoketene Acetals.
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- Masaki Yukio
- Gifu Pharmaceutical University
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- Miura Tsuyoshi
- Gifu Pharmaceutical University
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- Ochiai Masahito
- Gifu Pharmaceutical University
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A typical π-acid tetracyanoethylene and capto-dative olefin dicyanoketene acetals were found to catalyze stereospecific alcoholysis of epoxides at the ambient temperature to 50 °C in good yields. Mildness and significant chemoselectivity of the catalysts were demonstrated by intactness of tetrahydropyranyl ether and ethylene acetal groups. A novel regioselectivity associated with anchimeric assistance of the ethereal group on the side chain was observed in the ring opening reaction of the 1,2-disubstituted epoxides.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 69 (1), 195-205, 1996
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204127589120
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- NII論文ID
- 10008898718
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- NII書誌ID
- AA00580132
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- ISSN
- 13480634
- 00092673
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可