Rh(I)-Catalyzed Dehydrogenative Silylation of Divinylsilanes with Dimethylphenylsilane

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Author(s)

    • KAWANAMI Yukio
    • Department of Chemical Engineering, Tokyo Institute of Technology
    • YAMAMOTO Keiji
    • Department of Chemical Engineering, Tokyo Institute of Technology

Abstract

Rh(I)-catalyzed dehydrogenative silylation was selectively carried out by using divinylsilanes and half an equimolar amount of trialkylsilanes under ambient conditions to give 1,2-disilylethene and ethylvinylsilane derivatives in equimolar amounts. The mechanistic aspects for the dehydrogenative silylation were discussed in terms of the consecutive migratory insertions of the alkene moiety into both Rh–Si and Rh–H bonds which are formed by an oxidative addition of the hydrosilane to the Rh(I) catalyst precursor.

Journal

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 69(4), 1117-1124, 1996-04-15

    The Chemical Society of Japan

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Codes

  • NII Article ID (NAID)
    10008902402
  • NII NACSIS-CAT ID (NCID)
    AA00580132
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    00092673
  • Data Source
    CJP  J-STAGE 
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