A Willgerodt-Kindler Type Selenation of Dihalomethane Derivatives, Chloroform, and Sodium Trichloroacetate by Treating with a Base, Elemental Selenium, and an Amine.

• Shimada Kazuaki

  Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate University

• Yamaguchi Minoru

  Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate University

• Sasaki Tohru

  Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate University

• Ohnishi Kenji

  Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate University

• Takikawa Yuji

  Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate University

書誌事項

タイトル別名

• Willgerodt Kindler Type Selenation of D

抄録

Treatment of dihalomethane derivatives, chloroform, or sodium trichloroacetate with elemental selenium in the presence of NaH and an excess amount of an amine gave the corresponding selenoamides, selenoureas, and bis(selenocarbamoyl) triselenides in modest yields. These products were afforded from reactive intermediates related to “selenocarbonyl halides” and “selenophosgenoids” generated by the reaction of dichloromethanide ions and trichloromethanide ion with N-alkylated aminopolyselenide species (R₂N–(Se)_n⁻).

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 69 (8), 2235-2242, 1996

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204121714688
• NII論文ID: 10008907116
• NII書誌ID: AA00580132
• DOI: 10.1246/bcsj.69.2235
• ISSN: 13480634
• ISSN: 00092673
• NDL書誌ID: 4060542
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4060542
• Web Site: https://academic.oup.com/bcsj/article-pdf/69/8/2235/56196546/bcsj.69.2235.pdf
• 本文言語コード: en
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