A Willgerodt-Kindler Type Selenation of Dihalomethane Derivatives, Chloroform, and Sodium Trichloroacetate by Treating with a Base, Elemental Selenium, and an Amine.

• Shimada Kazuaki

  Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate University

• Yamaguchi Minoru

  Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate University

• Sasaki Tohru

  Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate University

• Ohnishi Kenji

  Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate University

• Takikawa Yuji

  Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate University

Bibliographic Information

Other Title

• Willgerodt Kindler Type Selenation of D

Abstract

Treatment of dihalomethane derivatives, chloroform, or sodium trichloroacetate with elemental selenium in the presence of NaH and an excess amount of an amine gave the corresponding selenoamides, selenoureas, and bis(selenocarbamoyl) triselenides in modest yields. These products were afforded from reactive intermediates related to “selenocarbonyl halides” and “selenophosgenoids” generated by the reaction of dichloromethanide ions and trichloromethanide ion with N-alkylated aminopolyselenide species (R₂N–(Se)_n⁻).

Journal

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 69 (8), 2235-2242, 1996

  The Chemical Society of Japan

Keywords

• General Chemistry

Details

• CRID: 1390001204121714688
• NII Article ID: 10008907116
• NII Book ID: AA00580132
• DOI: 10.1246/bcsj.69.2235
• ISSN: 13480634
• ISSN: 00092673
• NDL BIB ID: 4060542
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4060542
• Web Site: https://academic.oup.com/bcsj/article-pdf/69/8/2235/56196546/bcsj.69.2235.pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed