Low-Water-Content Diazomethane-d2 and Its Isotopic Assay

• Paolo Strazzolini

• Angelo G. Giumanini

• Giancarlo Verardo

書誌事項

タイトル別名

• Low-Water Content Diazomethane d2 and I

抄録

A multiple D2O–CH2N2 exchange followed by a final anhydrification with K2CO3 gave an alcohol-free low-water-content ether solution of CD2N2. Procedural improvements for the exchange are reported. The extent of deuteration with a quantitative evaluation of the actual species present in any solution of diazomethane could be determined by a GC-MS analysis and 1H NMR spectrometry on a suitable derivative. In addition, a procedure for the quantitative determination of water in diazomethane solutions has been developed.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 69 (10), 2943-2946, 1996-10

  Tokyo : Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1520573331023793536
• NII論文ID: 10008909877
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.69.2943
• NDL書誌ID: 4098829
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4098829
• Web Site: https://academic.oup.com/bcsj/article-pdf/69/10/2943/56245332/bcsj.69.2943.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
• データソース種別:
  • NDL
  • Crossref
  • CiNii Articles