Derivative-State Analysis of a Sequential Intramolecular Vibrational Energy Re-distribution

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Abstract

The Mori expansion adapted to pure-state dynamics is shown to be useful for analyzing a sequential intramolecular vibrational energy re-distribution (IVR). The expansion produces non-stationary basis states, “derivative states”, which form a chain of mutually interacting quantum states beginning at a given initial state. An analysis based on this chain clearly demonstrates how the Hilbert space of quantum states is explored in sequential IVR. The derivative states can be classified into several “generations”, and, thereby, a genealogy of quantum states can be discussed.

Journal

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 69(11), 3037-3046, 1996-11-15

    The Chemical Society of Japan

References:  31

Codes

  • NII Article ID (NAID)
    10008910328
  • NII NACSIS-CAT ID (NCID)
    AA00580132
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    00092673
  • NDL Article ID
    4098841
  • NDL Source Classification
    ZP1(科学技術--化学・化学工業)
  • NDL Call No.
    Z53-B35
  • Data Source
    CJP  NDL  J-STAGE 
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