Derivative-State Analysis of a Sequential Intramolecular Vibrational Energy Re-distribution

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  • Derivative State Analysis of a Sequenti

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<jats:title>Abstract</jats:title> <jats:p>The Mori expansion adapted to pure-state dynamics is shown to be useful for analyzing a sequential intramolecular vibrational energy re-distribution (IVR). The expansion produces non-stationary basis states, “derivative states”, which form a chain of mutually interacting quantum states beginning at a given initial state. An analysis based on this chain clearly demonstrates how the Hilbert space of quantum states is explored in sequential IVR. The derivative states can be classified into several “generations”, and, thereby, a genealogy of quantum states can be discussed.</jats:p>

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