Synthesis and Mercurophilic Properties of 2,2'-Oxybis(ethylenethio)ditropone and α-[2-(2-Troponylthio)ethyl]-ω-(2-troponylthio)oligo(oxyethylene)

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Abstract

The condensation reactions of 2-(<i>p</i>-tolylsulfonyloxy)tropone with 2,2′-oxydiethanethiol and its <i>α</i>-(2-sulfanylethyl)-<i>ω</i>-sulfanyloligo(oxyethylene) derivatives afforded 2,2′-oxybis(ethylenethio)ditropone and <i>α</i>-[2-(2-troponylthio)ethyl]-<i>ω</i>-(2-troponylthio)oligo(oxyethylene). Reflecting the acyclic nature of the polyethylene glycol moiety, they formed the complexes with various metal ions. Among them, mercury(II) salts were exclusively transported through a liquid membrane at least under the conditions used.

Journal

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 70(1), 231-237, 1997-01-15

    The Chemical Society of Japan

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Codes

  • NII Article ID (NAID)
    10008915344
  • NII NACSIS-CAT ID (NCID)
    AA00580132
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    00092673
  • NDL Article ID
    4142535
  • NDL Source Classification
    ZP1(科学技術--化学・化学工業)
  • NDL Call No.
    Z53-B35
  • Data Source
    CJP  NDL  J-STAGE 
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