Facile Chemical Dehydrogenation of α-Amino Acids Chelated to a Ruthenium(II) Ion:(α-Imino acidato)bis(1, 10-phenanthroline)ruthenium(II) Complexes^<1)>

この論文にアクセスする

この論文をさがす

著者

抄録

(<i>α</i>-Amino acidato)ruthenium(II) complexes were dehydrogenated to give (<i>α</i>-imino acidato)ruthenium(II) complexes by chemical oxidation. (<i>α</i>-Imino acidato)ruthenium(II) complexes, [Ru<sup>II</sup>{N(R<sup>1</sup>)=C(R<sup>2</sup>)CO<sub>2</sub>}(phen)<sub>2</sub>]<sup>+</sup> (R<sup>1</sup> = H, Me, or Bn, R<sup>2</sup> = H; R<sup>1</sup> = H or Me, R<sup>2</sup> = Me; R<sup>1</sup>, R<sup>2</sup> = –(CH<sub>2</sub>)<sub>3</sub>–) were obtained from the (<i>α</i>-amino acidato)ruthenium(II) complexes (glycinato, <i>N</i>-Me-glycinato, <i>N</i>-Bn-glycinato, (<i>S</i>)-alaninato, <i>N</i>-Me-(<i>S</i>)-alaninato, and (<i>S</i>)-prolinato complexes) by using diammonium cerium(IV) nitrate (CAN) as an oxidizing reagent. On the other hand, in the presence of hydrogen peroxide, the <i>α</i>-imino acidato complexes were converted to the corresponding <i>α</i>-imino acidato complexes, except for the glycinato and (<i>S</i>)-alaninato complexes. In particular, the iminoacetatoruthenium(II) complex, [Ru(NH=CHCO<sub>2</sub>)(phen)<sub>2</sub>]<sup>+</sup>, was synthesized for the first time by this method using CAN as an oxidizing reagent. Dehydrogenation with CAN is more facile and versatile than any other method that we have ever examined.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 70(5), 1069-1075, 1997-05-15

    The Chemical Society of Japan

参考文献:  35件中 1-35件 を表示

  • <no title>

    YAMAGUCHI M.

    the 30th International Conference on Coordination Chemistry Abstr, S2-41, 1994

    被引用文献1件

  • <no title>

    DROK K. J.

    Aust. J. Chem. 46, 1557, 1993

    被引用文献1件

  • <no title>

    YAMAGUCHI M.

    J. Am. Chem. Soc. 106, 8293, 1984

    被引用文献1件

  • <no title>

    YAMAGUCHI M.

    Bull. Chem. Soc. Jpn. 67, 1341, 1994

    被引用文献2件

  • <no title>

    HARROWFIELD J. M.

    J. Am. Chem. Soc. 96, 2634, 1974

    被引用文献1件

  • <no title>

    HARROWFIELD J. M.

    J. Am. Chem. Soc. 101, 1514, 1979

    被引用文献1件

  • <no title>

    HAMMERSHOI A.

    J. chem. Soc., Chem. Commun. 1988, 1226

    被引用文献1件

  • <no title>

    HAMMERSHOI A.

    Inorg. Chem. 29, 4525, 1990

    被引用文献1件

  • <no title>

    HARTSHORN R. M.

    Aust. J. Chem. 45, 5, 1992

    被引用文献1件

  • <no title>

    CHONG E. K.

    J. Am. Chem. Soc. 107, 2015, 1985

    被引用文献1件

  • <no title>

    YAMAGUCHI M.

    36th Symposium on Coordination Chemistry Abstr, NO 3A10, 1986

    被引用文献1件

  • <no title>

    YASHIRO M.

    Inorg. Chem. 33, 1003, 1994

    被引用文献1件

  • <no title>

    YAMAGUCHI M.

    Inorg. Chem. 32, 2981, 1993

    被引用文献2件

  • <no title>

    YAMAGUCHI M.

    Inorg. Chem. 35, 143, 1996

    被引用文献3件

  • <no title>

    MEDER J.

    Chem. Ber. 117, 827, 1984

    被引用文献1件

  • <no title>

    WAGNER B.

    Chem. Ber. 112, 1031, 1989

    被引用文献1件

  • <no title>

    LANE B. C.

    J. Chem. Soc., Chem. Commun. 1971, 1618

    被引用文献1件

  • <no title>

    MAHONEY D. F.

    Inorg. Chem. 12, 2561, 1973

    被引用文献4件

  • <no title>

    DIAMOND S. E.

    J. Am. Chem. Soc. 97, 2661, 1975

    被引用文献3件

  • <no title>

    BROWN G. M.

    Inorg. Chem. 15, 190, 1976

    被引用文献4件

  • <no title>

    KEENE F. R.

    J. Am. Chem. Soc. 98, 1884, 1976

    被引用文献2件

  • <no title>

    ADCOCK P. A.

    Inorg. Chem. 23, 2336, 1894

    被引用文献1件

  • <no title>

    WHEBELL G. W.

    Aust. J. Chem. 39, 2027, 1986

    被引用文献1件

  • <no title>

    BERHARD P.

    Inorg. Chem. 27, 2754, 1988

    被引用文献1件

  • <no title>

    BERHARD P.

    J. Am. Chem. Soc. 111, 597, 1989

    被引用文献1件

  • <no title>

    HO T. -L.

    Synthesis 1973, 347

    被引用文献4件

  • <no title>

    BENDAHL L.

    J. Chem. Soc., Chem. Commun. 1996, 1649

    被引用文献1件

  • <no title>

    LAY P. A.

    Inorg. Synth. 24, 291, 1986

    被引用文献1件

  • <no title>

    VAGG R.

    Inorg. Chim. Acta 58, 101, 1982

    被引用文献1件

  • <no title>

    LAY P. A.

    J. Am. Chem. 104, 6161, 1982

    被引用文献1件

  • <no title>

    RIDD M. J.

    J. Am. Chem. Soc. 103, 5733, 1981

    被引用文献2件

  • <no title>

    KEENE F. R.

    J. Am. Chem. Soc. 105, 7075, 1983

    被引用文献3件

  • <no title>

    DA COSTA FERREIRA A. M.

    J. Chem. Soc. 1983, 2051

    被引用文献1件

  • <no title>

    GOTO M.

    Inorg. Chem. 24, 582, 1985

    被引用文献3件

  • <no title>

    KURODA Y.

    Inorg. Chem. 28, 2163, 1989

    被引用文献3件

各種コード

  • NII論文ID(NAID)
    10008918633
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • NDL 記事登録ID
    4219899
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z53-B35
  • データ提供元
    CJP書誌  NDL  J-STAGE 
ページトップへ