Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by (S)-2-(N,N-Disubstituted aminomethyl)pyrrolidine

• Asami Masatoshi

• Inoue Seiichi

Bibliographic Information

Other Title

• Enantioselective Addition of Diethylzin

Abstract

The enantioselective addition of diethylzinc to aldehydes in the presence of a catalytic amount of several chiral diamines, (S)-2-(N,N-disubstituted aminomethyl)pyrrolidines, was studied. Relatively high selectivity was achieved in the case of aromatic aldehydes by employing 15 mol% of (S)-2-(1-pyrrolidinylmethyl)pyrrrolidine.

Journal

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 70 (7), 1687-1690, 1997-07

  Tokyo : Chemical Society of Japan

Keywords

• General Chemistry

Details

• CRID: 1522262179614828160
• NII Article ID: 130004058158
• NII Article ID: 10008920927
• NII Book ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.70.1687
• NDL BIB ID: 4260309
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4260309
• Web Site: https://academic.oup.com/bcsj/article-pdf/70/7/1687/56195567/bcsj.70.1687.pdf
• Text Lang: en
• NDL Source Classification:
  • ZP1(科学技術--化学・化学工業)
• Data Source:
  • NDL
  • Crossref
  • CiNii Articles