The Photolyses of 2, 6- and 2, 4-Difluorohalobenzenes

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Abstract

Photolyses of 2,6- and 2,4-difluorobromobenzenes in acetonitrile gave isomerized and brominated products in addition to 1,3-difluorobenzene produced by the dehalogenation. The reactions were compared with similar reactions of the corresponding chloro- and iodoarenes. In general, photolytic cleavage of the C–X bond of 2,6-difluorohalo(X)benzene was shown to proceed more easily than the corresponding 2,4-difluorohalo compound.

Journal

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 70(8), 1875-1878, 1997-08-15

    The Chemical Society of Japan

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Codes

  • NII Article ID (NAID)
    10008921755
  • NII NACSIS-CAT ID (NCID)
    AA00580132
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    00092673
  • NDL Article ID
    4277769
  • NDL Source Classification
    ZP1(科学技術--化学・化学工業)
  • NDL Call No.
    Z53-B35
  • Data Source
    CJP  NDL  J-STAGE 
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