Structures of Tetrakis(t-butylammonium) Diperoxotetramolybdate(4-) and -tungstate(4-)

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Abstract

Hydrogen-bonded columnar structures have been observed in tetrakis(<i>t</i>-butylammonium) diperoxotetramolybdate(4−) (<b>1</b>) and -tungstate(4−) (<b>2</b>). <b>1</b>, [(CH<sub>3</sub>)<sub>3</sub>CNH<sub>3</sub>]<sub>4</sub>[Mo<sub>4</sub>O<sub>12</sub>(O<sub>2</sub>)<sub>2</sub>], crystallizes in the tetragonal space group <SUB></SUB> with <i>a</i> = 16.312(2), <i>c</i> = 6.352(1) Å, <i>V</i> = 1690.2(5) Å<sup>3</sup>, <i>Z</i> = 2. <b>2</b>, [(CH<sub>3</sub>)<sub>3</sub>CNH<sub>3</sub>]<sub>4</sub>[W<sub>4</sub>O<sub>12</sub>(O<sub>2</sub>)<sub>2</sub>], crystallizes in the tetragonal form, <SUB></SUB>, with <i>a</i> = 16.488(3), <i>c</i> = 6.349(2) Å, <i>V</i> = 1725.9(9) Å<sup>3</sup>, <i>Z</i> = 2. In each crystal, four <i>t</i>-butylammonium cations bridge two [M<sub>4</sub>O<sub>12</sub>(O<sub>2</sub>)<sub>2</sub>]<sup>4−</sup> (M = Mo, W) anions through hydrogen bonds to terminal and bridging oxo-ligands to make a columnar structure along the <i>c</i> axis.

Journal

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 70(9), 2101-2105, 1997-09-15

    The Chemical Society of Japan

References:  17

Codes

  • NII Article ID (NAID)
    10008922702
  • NII NACSIS-CAT ID (NCID)
    AA00580132
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    00092673
  • NDL Article ID
    4307568
  • NDL Source Classification
    ZP1(科学技術--化学・化学工業)
  • NDL Call No.
    Z53-B35
  • Data Source
    CJP  NDL  J-STAGE 
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