Photoreduction of Hydrogencarbonate or Ethylene Catalyzed by Trisodium Trisulfonatophthalocyaninatozincate(II)

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Author(s)

    • NISHIE Kenji
    • Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University
    • SUGIMORI Tamotsu
    • Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University
    • HANDA Makoto
    • Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University

Abstract

In an aqueous dimethyl sulfoxide (DMSO) solution of triethanolamine (TEOA), the photosensitizer of the title complex (<b>1</b>), and 1,1′-dimethyl-4,4′-bipyridinium dichloride (MVCl<sub>2</sub>), MV<sup>•+</sup> radicals were formed upon irradiation with visible light; the photoreduction proceeded with light from both the B- (340 nm) and Q- (674 nm) band wavelengths of <b>1</b>. <br>The photoreduction of hydrogencarbonate to methane was performed in an aqueous DMSO solution of an electron donor, <b>1</b>, MVCl<sub>2</sub>, and ruthenium colloid upon irradiation with visible light. Ethylene was also photoreduced to ethane upon the irradiation of an aqueous solution of an electron donor, <b>1</b>, MVCl<sub>2</sub>, and palladium colloid.

Journal

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 70(9), 2107-2110, 1997-09-15

    The Chemical Society of Japan

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Codes

  • NII Article ID (NAID)
    10008922720
  • NII NACSIS-CAT ID (NCID)
    AA00580132
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    00092673
  • NDL Article ID
    4307569
  • NDL Source Classification
    ZP1(科学技術--化学・化学工業)
  • NDL Call No.
    Z53-B35
  • Data Source
    CJP  NDL  J-STAGE 
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